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Question

How do you know if enthalpy is positive or negative ?


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Solution

  • The enthalpy is positive in case of an endothermic reaction where the energy is taken from the surroundings
  • The given example shown below the dissociation of ammonia into nitrogen and hydrogen is an example of endothermic reaction.

2NH3(g)N2(g)+3H2(g);H=+92.2kJ

  • In case of an exothermic reaction, the enthalpy is negative as the energy is released from the reaction.
  • The given example below shown the formation of ammonia from nitrogen and hydrogen is an example of exothermic reaction:

N2(g)+3H2(g)2NH3(g);H=-92.2kJ


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