Molar mass of calcium = 40 g/mol
Therefore, 40 g of calcium = 1 mole of calcium
No of moles in 4 g =
Now, no of atoms in one mole of any substance remains constant, i.e 6.022 1023
So 0.1 mol of calcium will contain same no of atoms as in 0.1 mol of neon.
Molar mass of neon = 20 g/mol
Therefore, 20 g of neon = 1 mole of neon​
0.1 mol will contain 2 g of neon
Hence 2 gm of neon will have the same no of atom as in 4 gm of calcium.