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Question

How many litres of ethane would be produced when 2.62g of vinyl magnesium bromide is treated with 224ml of ethyne at STP.

A
0.224 litre
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B
0.08 litre
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C
0.448 litre
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D
1.12 litre
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Solution

The correct option is C 0.448 litre
2CH2=CHMgBr+ChCH2CH3CH3+MgBrCCMgBr
milli mole of ethyne = 224ml22.4l=10millimol
milli mole of vinyl magnesium bromide =2.62M×1000
=2.62131×1000=20mmol
mill mole of ethane generated = 2×10=20mMol
=20×103×22.4 litre
=0.448 litre

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