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Question

How many of the species are paramagnetic?

N2O, NO, NO2, O2, NO+2, NO+, CO+

A
2
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B
3
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C
5
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D
4
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Solution

The correct option is D 4
Number of valance electrons in N2O=5+6+5=16
All electrons can be paired up and there is no free electron. N2O molecule is therefore diamagnetic.

Number of valance electrons in NO=5+6=11
All electrons can not be paired up and there is an odd electron responsible for magnetism. NO molecule is therefore paramagnetic.

Number of valance electrons in NO2=5+6+6=17
All electrons can not be paired up and there is an odd electron responsible for magnetism. NO2 molecule is therefore paramagnetic.

Number of valance electrons in O2=6+6=12
All electrons can be paired up and there is no free electron. O2 molecule is exception and is paramagnetic.

Number of valance electrons in NO+2=5+6+61=16
All electrons can be paired up and there is no free electron. NO+2 molecule is therefore diamagnetic.

Number of valance electrons in NO+=5+61=10
All electrons can be paired up and there is no free electron. NO+ molecule is therefore diamagnetic.

Number of valance electrons in CO+=4+61=9
All electrons can not be paired up and there is an odd electron. CO+ molecule is therefore paramagnetic.

Overall 4 species are paramagnetic including NO, NO2, O2 and CO+

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