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Standard XII
Chemistry
Geometrical Isomerism in Octahedral Geometry
How many ster...
Question
How many stereo-isomers of following compound are predicted by the 2
n
rule?
C
2
H
5
−
C
|
H
−
C
|
H
−
C
H
3
C
l
B
r
A
2
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B
4
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C
8
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D
16
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Solution
The correct option is
B
4
C
2
H
5
−
C
|
∗
H
−
C
|
∗
H
−
C
H
3
C
l
B
r
The 2 chiral
C
atoms are marked by
∗
When 2 chiral carbon atoms are present, the number of stereoisomers are
2
n
=
2
2
=
4
.
So, 4 stereoisomers are predicted by the
2
n
rule.
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0
Similar questions
Q.
How many geometrical isomers are possible for the given compound?
C
H
3
−
C
H
=
C
H
−
C
H
=
C
H
−
C
2
H
5
Q.
The number of geometrical isomers in the following compound is:
C
H
3
−
C
H
=
C
H
−
C
H
=
C
H
−
C
2
H
5
Q.
Which of the following is/are correctly matched?
Compound
Number of geometric isomer
a.
C
H
3
−
C
H
=
C
H
−
C
H
=
C
H
−
C
2
H
5
4
b.
C
H
3
−
(
C
H
=
C
H
)
4
−
C
H
3
2
c.
H
2
C
=
C
H
−
C
H
=
C
H
2
2
4
+
2
1
=
10
d.
C
H
3
−
(
C
H
=
C
H
)
5
−
C
H
3
2
4
+
2
2
=
20
Q.
Which of the following compound give racemic mixture on nucleophilic substitution?
(a)
C
H
3
−
C
H
|
C
2
H
5
−
B
r
(b)
C
H
3
−
B
r
|
C
|
C
2
H
5
−
C
H
3
(c)
C
2
H
5
−
C
H
|
C
2
H
5
−
C
H
2
B
r
Q.
Which of the following compounds will give racemic mixture of nucleophilic substitution by
O
H
−
ion?
(i)
C
H
3
−
C
H
|
C
2
H
5
−
B
r
(ii)
C
H
3
−
B
r
|
C
|
C
2
H
5
−
C
H
3
(iii)
C
H
3
−
C
H
|
C
2
H
5
−
C
H
2
B
r
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