The correct option is A 1.33×1022
The reaction for the dehydration of sucrose is C12H22O11→12C+11H2O.
Thus, from one molecule of sucrose, 11 molecules of water are removed.
0.684 g of sucrose corresponds to 0.684342=0.002 moles which on dehydration will give 0.002×11=0.022 moles of water.
This corresponds to 0.022×6.023×1023=1.33×1022 water molecules.