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Question

How will you convert ethanal into the following compounds?
(i) Butane-1,3-diol (ii) But-2-enal (iii) But-2-enoic acid

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Solution

(i) Ethanal into Butane-1,3-diol
Aldol condensation (in presence of dil NaOH) followed by reduction with sodium borohydride.
(ii) Ethanal into But-2-enal
Aldol condensation (in presence of dil NaOH) followed by dehydration.
(iii) Ethanal into But-2-enoic acid
Aldol condensation (in presence of dil NaOH) followed by dehydration and oxidation with Tollen's reagent.
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