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Friedel Crafts Alkylation, Acylation

How will you ...

Question

How will you obtain 1 bromoprone from propene

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Solution

Dear Student
We can convert propene to 1-Bromopropane by adding HBr in the presence of Hydrogen Peroxide(H₂O₂).
It can be seen in the following equation-
$C H_{3} - C H = C H_{2} + H B r \overset{H_{2} O_{2}}{\to C H_{3}} - C H - C H_{2} B r$
This is Addition reaction and this addition is according to the Anti-Markonikov's Rule.
This effect is known as Khrash Effect.
Regards

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How the following conversions can be carried out?

(i) Propene to propan-1-ol

(ii) Ethanol to but-1-yne

(iii) 1-Bromopropane to 2-bromopropane

(iv) Toluene to benzyl alcohol

(v) Benzene to 4-bromonitrobenzene

(vi) Benzyl alcohol to 2-phenylethanoic acid

(vii) Ethanol to propanenitrile

(viii) Aniline to chlorobenzene

(ix) 2-Chlorobutane to 3, 4-dimethylhexane

(x) 2-Methyl-1-propene to 2-chloro-2-methylpropane

(xi) Ethyl chloride to propanoic acid

(xii) But-1-ene to n-butyliodide

(xiii) 2-Chloropropane to 1-propanol

(xiv) Isopropyl alcohol to iodoform

(xv) Chlorobenzene to p-nitrophenol

(xvi) 2-Bromopropane to 1-bromopropane

(xvii) Chloroethane to butane

(xviii) Benzene to diphenyl

(xix) tert-Butyl bromide to isobutyl bromide

(xx) Aniline to phenylisocyanide

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