Hybridization of AsF−6
In the AsF−6, the central atom is Arsenic(As) having atomic number 33.
Electronic configuration of As(33)=[Ar]3d104s24p3.
So, As has five electrons in the valence shell. So, it can have five single bonds with a fluorine atom and due to one negative charge, it forms one more single bond with a fluorine atom.
Hence, the total number of bond pairs =6
According to the VSEPR theory
No. of Bond pairs | No. of lone pair | Hybridization | Geometry | Shape |
6 | 0 | sp3d2 | Octahedral |