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Question

Hydrazine reacts with KIO3 In the presence of HCl as:
N2H4+IO3+2H++ClICI+N2+3H2O
The equivalent masses of N2H4 and KIO3 respectively are:

[KIO3=214]

A
8 and 53.5
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B
16 and 53.5
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C
8 and 35.6
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D
8 and 87
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Solution

The correct option is A 16 and 53.5
2N2H4++5IO3+2H++Cl+1ICl+0N2+3H2O
Equivalent weight of N2H4=MN2H42[2 to 0]
=322=16
Equivalent weight of KIO3=MKIO34[+5 to +1]
=2144=53.5

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