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Addition of Water

Hydrolysis of...

Question

Hydrolysis of methyl propanoate gives and ___.

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Solution

Hydrolysis of methyl propanoate gives propionic acid and methanol.

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^{'} X^{'} (C_{2} H_{4} O)

on oxidation gives

^{'} Y^{'} (C_{2} H_{4} O_{2}) .^{'} X^{'}

undergoes haloform reaction. On treatment with

H C N^{'} X^{'}

forms a product

^{'} Z

which on hydrolysis gives

2 -

hydroxy propanoic acid.
Write down structures of

^{'} X^{'}

^{'} Y

Q. A carbonyl compound gives a positive iodoform test but does not reduce Tollen's reagent or Fehling's solution. It forms a cyanohydrin with

H C N

, which on hydrolysis gives a hydroxy acid with a methyl side chain. The compound is:

Q. Compound 'A' reacts with

P C l_{5}

to give 'B' which on treatment with KCN followed by hydrolysis gave propanoic acid as the product. What is 'A'?

^{'} X^{'} (C_{2} H_{4} O)

on oxidation gives

^{'} Y^{'} (C_{2} H_{4} O_{2}) .^{'} X^{'}

undergoes haloform reaction. On treatment with

H C N^{'} X^{'}

forms a product

^{'} Z

which on hydrolysis gives

2 -

hydroxy propanoic acid.
Name of the product when

^{'} X^{'}

d i l . N a O H

Q. Hydrolysis of an ester gives acid

" A "

" B ", " A "

reduces Fehling's solution and oxidation of

B

A

. The ester is ?

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