I2 obtained from 0.1 mol of CuSO4 required 100 mL of 1M hypo solution. Hence, mole percentage of pure CuSO4 is:
A
100
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B
50
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C
25
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D
40
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Solution
The correct option is A100 The reactions that occur are given below: 2CuSO4+4KI→Cu2I2+I2+2K2SO4 I2+2Na2S2O3→2NaI+Na2S4O6 2CuSO4≡2Na2S2O3 CuSO4≡Na2S2O3 100 mL of 1 M hypo =0.1 mole hypo ≡0.1 mol pure CuSO4 Hence, it is 100% pure.