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Question

Identify electron-donating groups in resonance among the following:(A) CONH2 (B) NO2
(C)OCOCH3 (D) COCH3 (E) CHO (F) NHCOCH3

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Solution

Substituents with lone pairs (e.g. OCH3, NH2) on the atoms adjacent to the π-system are electron donating groups (EDG) in resonance systems.

And, substituents with π-bonds to electronegative atoms (e.g. C=O, NO2) adjacent to the π-system are electron withdrawing groups (EWG) in a resonating structure.

Therefore among the following groups electron-donating groups are:
(C)OCOCH3, and (F)NHCOCH3

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