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Question

Identify the correct statement for B2H6 from those given below:
(A) In B2H6, all B−H bonds are equivalent.
(B) In B2H6, there are four 3-centre-2-
electron bonds.
(C) B2H6 is a Lewis acid.
(D) B2H6 can be synthesized from both
BF3 and NaBH4
(E) B2H6 is a planar molecule.
Choose the most appropriate answer from the options given below:

A
(A) and (E) only
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B
(C) and (D) only
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C
(B), (C) and (E) only
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D
(C) and (E) only
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Solution

The correct option is B (C) and (D) only
Structure of B2H6

It has two 3-centre-2-electron 2-centre-2-electron bonds.
Hence, all BH bonds are not equivalent.
It is an electron deficient compound as the octet of boron is incomplete.
Hence, it can behave as a Lewis acid.
It can be synthesized from both BF3, and NaBH4
2BF3+6NaH450 K−−B2H6+6NaF
2NaBH4+I2B2H6+2Nal+H2

It is a non-planar molecule.
Hence, only Statements (C) and (D) are correct.

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