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Question

Identify the elements X and Y using the ionization energy values given below:

Ionization energy (kJ/mol).

1st

2nd

X

495

4563

Y

731

1450


A

X = F; Y = Mg

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B

X = Mg; Y = F

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C

X = Na; Y = Mg

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D

X = Mg; Y = Na

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Solution

The correct option is C

X = Na; Y = Mg


Explanation for the correct option:

Option (C ) is correct

  • Due to 2p6, noble gas electronic configuration, the second ionization enthalpy of Na is very high. That’s why has a large difference between IE1, and IE2
    Mg+ is 2p6, 3s1.
  • After the loss of one electron, Mg+ will be formed with noble gas electronic configuration. That’s why has less difference between IE1 and IE2, but their IE3 is very high.

X= Na; Y=Mg

Na → [Ne] 3s1 IE1 is very low but IE2 is very high due to the stable noble gas configuration of Na+.

Mg → [Ne] 3s2 , IE1&IE2LowIE3 is very high.

Explanation for the incorrect option:

(a) X = F; Y = Mg

The outermost orbit configuration of Flourine is not fully stable but highly stable for Mg.

(b) X = Mg; Y = F

The outermost orbit configuration of Mg is highly stable but for Flourine it's not fully stable.

(d) X = Mg; Y = Na

For this option first element is not fully stable, so this is not a correct option.

Final Answer: So the correct answer is option C


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