Given: Wt. of solute (w)=1.71g
Molar mass of solute (m)=342
Volume of solution (v)=500ml=0.5lt
Temperature (T)=300K
Gas constant (R)=0.0821ltatmK−1 mol−1
Osmotic pressure (π)=wRTmV=1.71×0.0821×300342×0.5=0.25atm
Thus, Osmotic pressure of the solution is 0.25atm.