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Question

If at 298 K the bond energies of CH,CC,C=C and HH bonds are respectively 414,347,615 and 435 kJ mol1, the value of enthalpy change for the reaction,

H2C=CH2(g)+H2(g)H3CCH3(g) at 298 K will be:

A
125 kJ
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B
+125 kJ
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C
250 kJ
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D
+250 kJ
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Solution

The correct option is A 125 kJ
H2C=CH2(g)+H2(g)H3CCH3(g)

According to Hess law,

ΔH=ΣEReactantsBondsBrokenΣEProductsBondsFormed

=[(C=C)+(HH)][(CC)+2(CH)]

=(615+435)[347+2(414)]

125KJ

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