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Question

If E0Fe2+/Fe=0.441 V and E0Fe3+/Fe2+=0.771 V, the standard emf of the reaction Fe+2Fe3+3Fe2+ will be:

A
1.653 V
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B
0.111 V
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C
0.330 V
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D
1.212 V
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Solution

The correct option is D 1.212 V
At anode:Fe2++2eFe E=0.441V


At cathode:2Fe3++2e2Fe2+ E=0.771V

Eocell= Eocathode- Eoanode

E=0.771(0.441)=1.212V

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