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Question

If M represents molecular mass of Br2 then what will be its equivalent mass if it undergoes disproportionation reaction as shown:

3Br2+6OH5Br+BrO3+3H2O


A
M2
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B
M10
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C
M2 + M10
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D

M6

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Solution

The correct option is C M2 + M10
Br2 dispropotionates, its equivalent weight is the sum of equivalent weights of the two half reactions.

2e+Br22Br (x=2) (reduction)

Br22BrO3+10e ('n'=10) (oxidation)
2x=0 2x-12=-2
2x=10

Ew = M2+M10

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