If Pt in PtCl4.2HCl has a coordination number of 6, how many moles of AgCl will 1 mole of the compound precipitate with excess AgNO3 ?
A
0
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B
1
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C
2
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D
4
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Solution
The correct option is A 0 Since the coordination number is 6, the compound should have six groups linked to Pt atom in coordination sphere.
It already has six groups linked to it and cannot lose any Cl− ion to form AgCl. Hence, no AgCl will be produced.