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Question

If the 1.58g of KMnO4 in acidic medium completely reacts with ferrous oxalate what weight (in gm) of ferrous oxalate is required?

A
2.73 gm
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B
4.73 gm
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C
11.19 gm
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D
5.62 gm
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Solution

The correct option is A 2.73 gm
FeC2O4nf=3

KMnO4nf=5

Moles of KMnO4=1.58158=0.01

Equivalents of KMnO4=moles×nf=0.01×5=0.05

Equivalents of FeC2O4=moles×nf=n×3=0.05

n=0.053

Weight of FeC2O4=n×142=2.73 gm

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