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Question

If the boiling point elevation constant and the boiling point of benzene are 2.16 K kg mol1 and 81.0 C respectively, calculate the boiling point of a solution formed when 5 g of C14H12 is dissolved in 15 g of benzene.

A
90 C
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B
75 C
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C
81 C
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D
85 C
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Solution

The correct option is D 85 C
ΔTb=kb×m
molality= number of moles of soluteweight of solvent×1000
Molar mass of C14H12 = 180 g/mol
molality=5/18015×1000=1.85 m
ΔTb=kb×m
=2.16×1.854 K
Boiling point of the solution = 85o C

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