The electrons involved in chemical bond formation will be 3d54s1
According to the given electronic configuration we can say that the element is a transition metal.
For transition elements, the ns and (n−1)d orbitals' electrons take part in the chemical bond formation. All other inner electrons are part of a fully filled shells so they are non reactive.
In the above electronic configuration the outermost subshells are 3d and 4s.
They have 5 and 1 electrons respectively in their subshell which will contribute to bond formation.
So, total electrons will be 6.