wiz-icon
MyQuestionIcon
MyQuestionIcon
1
You visited us 1 times! Enjoying our articles? Unlock Full Access!
Question

If true enter 1, else enter 0.
Both N and Cl has almost same electronegativity but later is not involved in H-bonding.
  1. 1

Open in App
Solution

The correct option is A 1
There is no (or very little) orbital mixing between the HOMO of chlorine and the LUMO of hydrogen. This is because chlorine is in row 3. As you move down the rows, the difference in the size between the hydrogen LUMO and the acceptor orbitals becomes larger resulting in poor overlap and less mixing (all the good acceptors are in group 2). Without orbital mixing, there is no hydrogen bond - only a dipole-dipole interaction.

flag
Suggest Corrections
thumbs-up
0
Join BYJU'S Learning Program
similar_icon
Related Videos
thumbnail
lock
Can Matter Change Its State?
CHEMISTRY
Watch in App
Join BYJU'S Learning Program
CrossIcon