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Question

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The HNH bond angle in NH3 is greater than HAsH bond angle in AsH3.
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Solution

The correct option is A 1

Hydride

NH3

PH3

AsH3

SbH3

H-M-H angle

107

92

91

90

This variation in bond angle can be explained on the basis of electronegativity of the central atom.

  • Since nitrogen atom is highly electronegative. So in NH3 there is high electron density around the N atom which causes greater repulsions between the electron pairs around the N atom resulting in maximum bond angle.
  • Since electronegativity decreases down the group, the electron density also decreases and consequently the repulsive interactions between the electron pairs also decrease thereby decreasing the bond angle H-M-H.

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