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The side by side overlap that forms a π-bond makes a molecule resistant of twisting and prevents atoms with larger radii in forming multiple bonds.
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multiple bonds are formed when an atom forms a sigma bond by using an sp or sp2 hybrid orbital and one or more pi bonds by using unhybridized p-orbitals. the side-by-side overlap that forms a pi bond makes a molecule resistant to twisting, results in bonds weaker than sigma bonds, and prevents atoms with large radii from forming multiple bonds.

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