Consider a water drop at the centre of a huge ice cube. Initially, ice starts absorbing heat from the water drop and the temperature of water starts decreasing and becomes 0oC- same as that of ice.So, thermal equilibrium is reached. During thermal equilibrium, ice cannot absorb heat from water, as both have same temperature. If the water 0oC has to be frozen to ice, the 80 cal of heat should be removed from every gram of water. This is not possible due to thermal equilibrium and hence the water drop cannot be frozen.