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Question

In a hydrogen atom, the electron and proton and bound at a distance of about 0.53 A. What is the minimum work required to free the electron, given that its kinetic energy in the orbit is half the magnitude of potential energy obtained? Taking the zero of the potential energy at infinite separation of the electron from proton

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Solution

Total energy =273.2 eV+13.6 eV=13.6 eV
The work required =13.6eV

The distance between electron-proton of a hydrogen atom, d=0.53A
Charge on an electron, q1=1.6×1019 C
Charge on a proton, q2=+1.6×1019 C
Now,
Potential energy of the system, pe = Potential energy at infinity separation - Potential energy at distance, d
pe=0q1q24πϵ0d (whereϵ0 is the permittivity of free space and 14πϵ0=9×109 Nm2C2)

pe=0(1.6×1019)2×9×1090.53×1010=43.7×1019 J=27.2eV

Since, kinetic energy in the orbit is half the magnitude of potential energy obtained
K.E=|27.2|2=13.6eV

Minimum work required = 27.2eV13.6eV=13.6 eV

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