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Question

In a reaction, 358 g of TiCl4 is reacted with 96 g of Mg. Calculate the % yield of Ti if 32 g of Ti is obtained from the reaction. (Molar mass of Ti = 48 g/mol, Mg = 24 g/mol)

A
35.46%
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B
66.86%
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C
85.76%
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D
48.34%
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Solution

The correct option is A 35.46%
TiCl4+2Mg2MgCl2+Ti
Moles of TiCl4=358190=1.88; moles of Mg =9624=4
Calculation of limiting reagent:
2 moles of Mg reacts with 1 mole of TiCl4
4 moles will react =12×4=2 moles of TiCl4
Hence TiCl4 is the limiting reagent.
1 mole of TiCl4 produces 1 mole of Ti
1.88 mole will produce 1.88 mole of Ti
Mass of 1.88 mole of Ti=1.88×48=90.24 g
% yield =actual yieldtheoretical yield×100=3290.24×100=35.46

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