Given reaction,
A + B2 → AB2
A limiting reagent determines the extent of a reaction. Its is the reactant which is the first to get consumed during a reaction, thereby causing the reaction to stop and limiting the amount of products formed.
(i) According to the given reaction, 1 atom of A will react with 1 molecule of B. Thus 200 molecules of B will react with 200 atoms of A, thereby leaving 100 atoms of A unused. Hence, B is the limiting reagent
(ii) According to the given reaction, 1 mole of A reacts with 1 mole of B. Thus, 2 moles of A will react with only 2 moles of B. As a result, 1 moles of B will not be consumed. Hence, A is the limiting reagent.