|ml|=1 thus, the magnetic quantum number =+1 and −1
(ms)=−12
n=4 can have suborbitals.
lmlms4s00+12−124p1−1–––,0,+1–––+12−124d2−2,−1–––,0,+1–––,+2+12−124f3−3,−2,−1–––,0,+1–––+2,+3+12−12
Thus underlined electrons with (ml=−1,+1) and spin −(12) are six.