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Question

In Calcium fluoride, having the fluorite structure, the coordination numbers for calcium ion (Ca2+) and fluoride ion (F) are

A
8 and 4
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B
4 and 8
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C
4 and 2
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D
6 and 6
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Solution

The correct option is A 8 and 4
The fluorite structure, seen in calcium fluoride, has the calcium ions in a face centered cubic array with the fluoride ions in all (8) of the tetrahedral holes. The fluoride ions have a coordination number of 4, and the calcium ions have a coordination number of 8.

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