In Carius method of estimation of halogens, 250 mg of an organic compound gave 141 mg of AgBr. The percentage of bromine in the compound is: (Atomic mass of Ag= 108, Br= 80)
A
24
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B
36
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C
48
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D
60
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Solution
The correct option is A 24 It is given that 141 mg of AgBr is obtained. So, moles of AgBr=141×10−3188 ∴ moles of Br=141×10−3188 ∴ mass of Br=141×10−3188×80 ∴ percentage of Br in organic compound= 141×10−3×80188×250×10−3×100=24%