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Question

In hot alkaline solution, Br2 disproportionates to Br and BrO3.
3Br2+6OH5Br+BrO3+3H2O
Hence, equivalent weight of Br2 is (mol. wt. =M) :

A
m/8
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B
7 m/5
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C
3 m/5
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D
2 m/3
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Solution

The correct option is C 3 m/5
In the disproportionation reaction, net equivalent weight = (Eq.wt.)O+(Eq.wt.)R
(Eq.wt.)O=M10
(Eq.wt.)R=M2
Net = M10+M2=0.6M

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