In metal deficiency defect
Cations are missing from the lattice points
In metal deficiency defect cations miss from their Lattice points, and to balance the negative charge the neighboring cation’s charge is increased. No change in charge of anion. So only option correct is (a)
Metal deficiency defect diagram.
In this diagram we can see Fe2+ left the lattice sites and to balance the charge with O2- ions charge of Fe2+ increased to +3.(Fe3+ ions)