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Question

In the complex FeK2[Fe(CN)6],

A
Both Fe atoms are in the same oxidation state.
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B
Both Fe atoms are in the different oxidation state.
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C
The coordination number of ion is 4.
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D
The complex is a high spin complex.
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Solution

The correct option is A Both Fe atoms are in the same oxidation state.
In Fe+2K+22[Fe+2(CN)6], both Fe atoms are in the same oxidation state.
As CN is a strong ligand so pairing of electron happens and low spin complex forms.
As here Fe is connected with 6 ligands so coordination number of ion is 6.

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