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Question

In the context of Hall-Heroult process for the extraction of Aluminium, which of the following statement is false?

A
CO and CO2 are produced in this process
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B
Al2O3 is mixed with CaF2 which lowers the melting point of the mixture and enhances the conductivity
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C
Al3+ is reduced at the cathode to form Al
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D
Na3AlF6 serves as the electrolyte
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Solution

The correct option is D Na3AlF6 serves as the electrolyte
In this process, carbon being the anode is oxidised to CO and CO2

At the cathode, Al3+ from Al2O3 is reduced to Al

Al2O3 is the electrolyte used, which is undergoing the redox process, here, Na3AlF6 serves as the solvent.

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