In the conversion of ethanol into methanol which of the following reagents will be used?
A
K2Cr2O7/H2SO4
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B
NaOH+CaO
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C
Cl2+aq.KOH
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D
All of these
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Solution
The correct option is D All of these CH3CH2OH[O]→K2Cr2O7/H2SO4CH3CHO[O]→K2Cr2O7/H2SO4CH3COOHNaOH+CaO→ΔCH4Cl2→CH3Claq.KOH→−KClCH3OH.
Ethanol eventually oxidizes to ethanoic acid with the help of K2Cr2O7/H2SO4 Decarboxylation of ethanoic acid gives methane, when chlorine is passed through methane forms methyl chloride. In presence of aq. KOH methanol is produced. Hence, all the reagents are required to convert ethanol to methanol. Option D is correct.