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Question

in the definition of calorimetry why particularaly 14.5-15-5 degree celsius is the number specified?

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Solution

Calorie is simply energy required to increase the temp. Of water by 1°c at standard atmosphere which is approximately 4.185 but there are may definations of calorific value

1)the amount of energy equal to exactly 4.184 joules = thermo chemical calorie

2)the amount of energy required to warm one gram of air-free water from 3.5 to 4.5 °C at standard atmospheric pressure.=4°c calorie

3)the amount of energy required to warm one gram of air-free water from 14.5 to 15.5 °C at standard atmospheric pressure. Experimental values of this calorie ranged from 4.1852 to 4.1858 J. = 15°c calorie.

So, it's standard value which is obtained from experiments.there are several other definitions


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