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Question

In the following electrochemical cell : Zn|Zn2+||H|(H2)Pt Ecell=cell. This will be when :

A
[Zn2+]=[H]=1M and pH2=1atm
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B
[Zn2+]=0.01M,[H=0.1M, and pH2=1atm
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C
[Zn2+]=1M,[H]=0.1M, and pH2=1atm
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D
None of the above
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Solution

The correct options are
A [Zn2+]=[H]=1M and pH2=1atm
B [Zn2+]=0.01M,[H=0.1M, and pH2=1atm

Cell reaction : Zn(s)+2H(aq)Zn2+(aq)+H2(g)

Ecell=Ecell0.05912log(Qcell)

For Ecell=E, Qcell=1

Ecell=Ecell,Qcell=1.0


a. Qcell=1×112=1

b. Qcell=1×0.01(0.1)2=1

c. Qcell=1×1(0.1)2=100


Hence, options A and B are correct.


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