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Question

In the following reaction sequence in aqueous solution, the species X, Y and Z, respectively, are:
S2O23Ag+XclearsolutionAg+Ywhiteprecipitatewith time−−−−Zblackprecipitate

A
[Ag(S2O3)2]3,Ag2S2O3,Ag2S
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B
[Ag(S2O3)3]5,Ag3SO3,Ag2S
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C
[Ag(SO3)z]3,Ag2S2O3,Ag
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D
[Ag(SO3)3]3,Ag2SO4,Ag
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Solution

The correct option is A [Ag(S2O3)2]3,Ag2S2O3,Ag2S
Ag++2S2O23[Ag(S2O3)2]3(X)Ag+Ag2S2O3()white ppt. (Y)(with time)−−−−−Ag2S()Black(Z)

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