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Question

In the reaction:

Na2CO3SO2ANa2CO3BElementS−−−−−ΔCI2D
find the oxidation state of S in product C ?

A
2
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B
6
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C
+5 and -1
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D
+5 and 0
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Solution

The correct options are
A 2
C +5 and -1
Options (A) and (C) are correct.

Na2CO3+2SO2+H2O2NaHSO3[A]+CO2

2NaHSO3+Na2CO32Na2SO3[B]+H2O+CO2

Na2SO3+SNa2S2O3[C]

2Na2S2O3+I2ΔNa2S4O6[D]+2NaI

Oxidation states of sulphur :
NaHSO3:(+6)
Na2SO3:(+6)
Na2S2O3:(+2) or (+5and1)
Na2S2O6:(+2) or (+5and0)

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