In the reversible reaction A+B⇌C+D, the concentration of each C and D at equilibrium was 0.8 mole/litre, then the equilibrium constant Kc will be (if initial concentration of A and B be will 1M each)-
A
6.4
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B
0.64
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C
1.6
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D
16.0
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Solution
The correct option is D16.0 The initial concentrations of A, B, C and D are 1M, 1M, 0M and 0M respectively. The equilibrium concentrations of A, B, C and D are 1−0.8=0.2M,1−0.8=0.2M, 0.8M and 0.8M respectively. The expression for the equilibrium constant is Kc=[C][D][A][B]=0.8×0.80.2×0.2=16.0.