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A Primer on Nucleophilies and Methods of Attack

In which of t...

Question

In which of the following alkyl halide a hydride shift occur upon addition of water?

$C H_{3} - B r | C | C H_{3} - C H_{2} - C H_{3}$

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$C H_{3} - C H | C H_{3} - B r | C H - C H_{3}$

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$C H_{3} - C H | C H_{2} - B r - C H_{2} - C H_{3}$

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$C H_{3} - C H | C H_{3} - C H_{2} - C H_{2} B r$

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Solution

The correct options are
B
$C H_{3} - C H | C H_{3} - B r | C H - C H_{3}$

C
$C H_{3} - C H | C H_{2} - B r - C H_{2} - C H_{3}$

D
$C H_{3} - C H | C H_{3} - C H_{2} - C H_{2} B r$

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Similar questions

C H_{3} - C H_{2} - C H_{2} - C H_{3} C o n c . H C l, A l C l_{3} - --------- \to C H_{3} - C H | C H_{3} - C H_{3}

S_{N} 2

K I

C H_{3} - C H_{2} - C H_{2} - C H_{2} - C l a n d C H_{3} - C H ∣ C H_{3} - C H_{2} - C l

(I) (I I)

C H_{3} - C H_{2} - C H_{2} - C l a n d C H_{3} - C H_{2} - C H_{2} - B r

(I) (I I)

C H_{3} - C H ∣ C H_{3} - C H_{2} - C H_{2} - C l a n d C H_{3} - C H_{3} ∣ C ∣ C H_{3} - C H_{2} C l

(I) (I I)

C H_{3} - C H_{2} - C H_{2} - B r ∣ C H - C H_{3} a n d C H_{3} - C H_{3} ∣ C H - C H_{2} - B r ∣ C H - C H_{3}

(I) (I I)

C H_{3} - O H | C H - C H_{2} - C H_{3} A l_{2} O_{3} - -- \to 573 K C H_{3} - C H = C H - C H_{3}

C H_{3} - C | C H_{3} H - C H_{2} - C H_{2} - O H

C H_{3} - O H | C | C H_{3} - C H_{2} - C H_{3}

C H_{3} C H_{3} | C H - O H | C H - C H_{3}

A, B, C

S_{N} 2

c o n c . H C l :

(a) C H_{3} - C H_{2} - O H A n h y Z n C l_{2} / △ - -------- \to C H_{3} - C H_{2} - C l

(b) C H_{3} - C H_{3} | C | C H_{3} - C H_{2} O H A n h y Z n C l_{2} / △ - -------- \to C H_{3} - C H_{1} | C | C H_{3} - C H_{2} - C H_{3}

(c) C H_{3} - O H | C | C H_{3} - C H_{3} A n h y Z n C l_{2} / △ - -------- \to C H_{3} - C l | C | C H_{3} - C H_{3}

(d) C H_{2} = C H - C H_{2} - O H A n h y Z n C l_{2} / △ - -------- \to C H_{2} = C H - C H_{2} - C l

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