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Question

In which of the following cell (s) : Ecell=Eocell?

A
Cu(s)|Cu2+(0.01M)||Ag+(0.1M)|Ag(s)
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B
Pt,H2(g)atm|pH=1||Zn2+(0.01M)|Zn(s)
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C
Pt,H2(g)atm|pH=1||Zn2+(1M)|Zn(s)
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D
Pt,H2(g)atm|H+=0.1M||Zn2+(0.01M)|Zn(s)
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Solution

The correct options are
A Cu(s)|Cu2+(0.01M)||Ag+(0.1M)|Ag(s)
C Pt,H2(g)atm|pH=1||Zn2+(0.01M)|Zn(s)
D Pt,H2(g)atm|H+=0.1M||Zn2+(0.01M)|Zn(s)
Ecell=E0cell0.0591nlogQ if Q=1
Ecell=E0cell
(A) Q=0.010.12=1 (B) Q=0.120.01=1
(C) Q=0.121=0.1 (D) Q=0.120.01=1

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