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Question

In which of the following compounds carbon is in highest oxidation state?

A
CH3Cl
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B
CCl4
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C
CHCl3
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D
CH2Cl2
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Solution

The correct option is B CCl4
Let the oxidation number of carbon be x.
Oxidation number of H=+1, Cl=1
(A) CH3Cl: x+3×1+(1)=0
x+31=0 or x=2
(B) CCl4: x+4×(1)=0
x4=0 or x=+4
(C) CHCl3: x+1+3×(1)=0
x+13=0 or x=+2
(D) CH2Cl2: x+2×1+2×(1)=0
x+22=0 or x=0
the highest oxidation state of carbon is +4 in CCl4

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