In which of the following is oxidation number fractional?
A
B4O10
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B
B2O3
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C
C5O2
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D
KO3
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Solution
The correct options are CC5O2 DKO3 The oxidation number is fractional in C5O2 and KO3 respectively. (A) Let X be the oxidation number of B in B4O10. 4X+10(−2)=0 4X=20 X=+5 (B) Let X be the oxidation number of B inB2O3 2X+3(−2)=0 2x=6 X=+3 (C) Let X be the oxidation number of C inC5O2 5X+2(−2) 5X=4 X=45 (D) Let X be the oxidation number of O inKO3 +1+3X X=−13