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Question

In which of the following process, the bond order increases and magnetic behaviour changes?

A
N2N+2
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B
C2C+2
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C
NONO+
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D
O2O+2
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Solution

The correct option is D NONO+

In NONO+ the bond order increases and magnetic behaviour changes.

NO has 15 electrons, its bond order =1/2[83]=2.5 and is paramagnetic; while NO+ has 14 electrons, , its bond order =1/2[82]=3 is diamagnetic.


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