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Question

In which of the following reaction(s) H2O2 acts as a reducing agent?

A
H2O2+2H++2e2H2O
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B
H2O22eO2+2H+
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C
H2O2+2e2OH
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D
H2O2+2OH2eO2+2H2O
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Solution

The correct option is D H2O2+2OH2eO2+2H2O
Losing or giving away electrons reduces the oxidation number/state of the species with which H2O2 reacts. Hence, in those cases, H2O2 will be acting as a reducing agent.

In reactions:
H2O22eO2+2H+

H2O2+2OH2eO2+2H2O

It is clear that H2O2 is losing electrons. Hence H2O2 acts as reducing agent in the above reactions.

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