In which of the following reactions does sulphurous acid function as an oxidising agent?
A
H2SO3+Br2+H2O→H2SO4+2HBr
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B
5H2SO3+2KIO3→I2+4H2SO4+H2O+K2SO4
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C
H2SO3+2H2S→3H2O+3S
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D
H2SO3+2FeCl3+H2O→H2SO4+2FeCl2+2HCl
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Solution
The correct option is CH2SO3+2H2S→3H2O+3S In H2SO3+2H2S→3H2O+3S reaction, H2SO3 acts as oxidising agent. In this reaction H2S is oxidised and converted into sulphur by using H2SO3.